PUBLICATIONS

Representative publications:

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Water Purification and Microplastics Removal using Magnetic Polyoxometalate SupportedIonic Liquid Phases (magPOMSILPs)” A. Misra, C. Zambrzycki, G. Kloker, A. Kotyrba, M. H. Anjass, I. Franco Castillo, S. G. Mitchell*, R. Güttel,* C. Streb, Angew. Chem. Int. Ed., 2019, DOI: 10.1002/ange.201912111

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Preventing fungal growth on heritage paper with antifungal and cellulase inhibiting magnesium oxide nanoparticles”

I. Franco Castillo, E. García Guillén, J. M. de la Fuente, F. de Silva* & S. G. Mitchell* J. Mater. Chem. B 2019, 7, 6412-6419 (2019 Emerging Investigators Special issue)

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“Polyoxometalates as alternative Mo precursors for methane dehydroaromatization on Mo/ZSM-5 and Mo/MCM-22 catalysts” I. Julian,* J. L. Hueso, N. Lara, A. Solé-Daurá, J. M. Poblet, S. G. Mitchell*, R. Mallada & J. Santamaría, Catal. Sci. Technol., 2019, 2019, 9, 5927-5942.

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“Polyoxometalate-Ionic Liquids (POM-ILs) as Anticorrosion and Antibacterial Coatings for Natural Stones” A. Misra, I. Franco Castillo, D. Müller, C. González, S. Eyssautier-Chuine, A. Ziegler, J. M. de la Fuente; S. G. Mitchell* & C. Streb.* Angew. Chem. Int. Ed., 2018, 57, 14926-14931.

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Effective in Vitro Photokilling by Cell-Adhesive Gold Nanorods, Á. Artiga, S. García-Embid, L. de Matteis*, S. G. Mitchell*, J. M. de la Fuente, Frontiers in Chemistry, 2018, 6, 234.

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A metamorphic inorganic framework that can be switched between eight single-crystalline states  C. Zhan, J. M. Cameron, D. Gabb , T. Boyd , R. S. Winter, L. Vilà-Nadal, S. G. Mitchell, S. Glatzel, J. Breternitz, D. H. Gregory, D.-L. Long, A. Macdonell & L. Cronin, Nature Communications 20178, 14185

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Removal of Multiple Contaminants from Water by Polyoxometalate-Supported Ionic Liquid Phases (POM-SILPs) S. Herrmann, L. De Matteis, J. M. de la Fuente, S. G. Mitchell* and C. Streb*, Angew. Chemie. Int. Ed. 2017, 56, 1667–1670.

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Gold nanoprism–nanorod face off: comparing the heating efficiency, cellular internalization and thermoablation capacity G. Alfranca, Á. Artiga, G. Stepien, M. Moros, S. G Mitchell* and Jesús M de la Fuente*,  Nanomedicine, 201611, 2903-2916.

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In vitro cell cytotoxicity profile and morphological response to polyoxometalate-stabilised gold nanoparticles I. Maicas Gabas, G. Stepien, M. Moros,* S. G. Mitchell* and Jesús M. de la Fuente, New J. Chem., 201640, 1039.

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Dissecting the molecular mechanism of apoptosis during photothermal therapy using gold nanoprisms M. Pérez-Hernández, P. del Pino, S. G. Mitchell, M. Moros, G. Stepien, B. Pelaz, W. Parak, E. Gálvez, J. Pardo and J. M. de la Fuente, ACS Nano, 2015, 9, 52–61

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The importance of a correct functionalization of gold and magnetic nanoparticles for bioapplications R. M. Fratila, S. G. Mitchell, P. del Pino, V. Grazú, J. M. de la Fuente, Langmuir, 2014, 30 (50), 15057–15071

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Simultaneous syntheses of polyoxometalates and metal nanoparticles from molecular precursors: redox-active microreactors and functional nanomaterials, S. G Mitchell* and J. M de la Fuente, Eur. J. Inorg. Chem. 2013, 32, 5517-5522

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The synergistic behavior of polyoxometalates and metal nanoparticles: From synthetic approaches to functional nanohybrid materials, S. G Mitchell* and J. M de la Fuente, J. Mater. Chem. 2012, 22, 18091-18100

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A MixedValence Manganese Cubane Trapped by Inequivalent Trilacunary Polyoxometalate LigandsS. G Mitchell, P. I. Molina, S. Khanra, H. N Miras, A. Prescimone, G. JT Cooper, R. S Winter, E. K Brechin, D.‐L. Long, R. J Cogdell, L. Cronin, Angew. Chemie. Int. Ed. 2011, 123, 9320-9323

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Face-directed self-assembly of an electronically active Archimedean polyoxometalate architectureS. G Mitchell, C. Streb, H. N Miras, T. Boyd, D.-L. Long, L. Cronin Nature Chemistry 2010, 2, 308-312 (Highlighted in Nature 2010, 464, 366)

Full publications list:

(49)  Water Purification and Microplastics Removal using Magnetic Polyoxometalate SupportedIonic Liquid Phases (magPOMSILPs)”

A. Misra, C. Zambrzycki, G. Kloker, A. Kotyrba, M. H. Anjass, I. Franco Castillo, S. G. Mitchell*, R. Güttel,* C. Streb, Angew. Chem. Int. Ed., 2019, DOI: 10.1002/ange.201912111

(48)  “A one-pot route for the synthesis of Au@Pd/PMo12/rGO as a dual functional electrocatalyst for ethanol electro-oxidation and hydrogen evolution reaction”

A. Ahmadpour, S. Khadempir, N. Ashraf, S. G. Mitchell, M. H. Ahangari, RSC Adv., 2019, 9, 37537-37545

(47)  “Polyoxometalates as alternative Mo precursors for methane dehydroaromatization on Mo/ZSM-5 and Mo/MCM-22 catalysts”

I. Julian,* J. L. Hueso, N. Lara, A. Solé-Daurá, J. M. Poblet, S. G. Mitchell*, R. Mallada & J. Santamaría

Catal. Sci. Technol., 2019, 2019, 9, 5927-5942

(46)  “Natural Polysaccharides for siRNA Delivery: Nanocarriers Based on Chitosan, Hyaluronic Acid, and Their Derivatives”

I. Serrano-Sevilla, Á. Artiga, S. G. Mitchell, L. De Matteis, J. M. de la Fuente, Molecules, 2019, 24, 2570.

(45)Preventing fungal growth on heritage paper with antifungal and cellulase inhibiting magnesium oxide nanoparticles”

I. Franco Castillo, E. García Guillén, J. M. de la Fuente, F. de Silva* & S. G. Mitchell* J. Mater. Chem. 2019, 7, 6412-6419 (2019 Emerging Investigators Special issue)

(44) “Current status and future perspectives of gold nanoparticle vectors for siRNA delivery”

Á. Artiga, I. Serrano, L. De Matteis, S. G. Mitchell, J. M. de la Fuente J. Mater. Chem. B, 2019, 7, 876.

(43) “Polyoxometalate-Ionic Liquids (POM-ILs) as Anticorrosion and Antibacterial Coatings for Natural Stones”

A. Misra, I. Franco Castillo, D. Müller, C. González, S. Eyssautier-Chuine, A. Ziegler, J. M. de la Fuente; S. G. Mitchell* & C. Streb.* Angew. Chem. Int. Ed., 2018, DOI: 10.1002/anie.201809893 (Cover)

(42) “Protection of 18th century paper using antimicrobial nano-magnesium oxide”

I. Franco Castillo, L. De Matteis,C. Marquina, E. García Guillén, J. M. de la Fuente & S. G. Mitchell*. International Biodegradation & Biodeterioration, 2019, 141, 79-86.

(41) “Effective in Vitro Photokilling by Cell-Adhesive Gold Nanorods”

Á. Artiga, S. García-Embid, L. De Matteis,* S. G. Mitchell* & J. M. de la Fuente, Front Chem. 2018, 6, 234.

(40) “Nanomateriales antimicrobianos para la preservación del patrimonio cultural”

S. G. Mitchell*, Sara Rivera-Fernández y Jesús M. de la Fuente, La Ciencia y el Arte VI, 2017.

(39) “Multiparametric analysis of anti-proliferative and apoptotic effects of gold nanoprisms on mouse and human primary and transformed cells and in vivo biodistribution and toxicity”

M. Pérez-Hernández, M. Moros, G. Stepien, P. del Pino, S. Menao, M. de la Heras, M. Arias, S. G. Mitchell, B. Pelaz, E. M. Gálvez, J. M. de la Fuente, J. Pardo, Particle Fibre & Toxicology 2017, 14, 41.

(38)  “Antimicrobial Activity of Polyoxometalate Ionic Liquids against Clinically Relevant Pathogens”

A.-L. Kubo, L. Kremer, S. Herrmann, S. G. Mitchell, O. M. Bondarenko, A. Kahru, C. Streb, ChemPlusChem, 2017, 82, 867–871

(37)  “POMzites: a family of zeolitic polyoxometalate frameworks from a minimal building block library”

T. Boyd, S. G. Mitchell, D. Gabb, D.-L. Long, Y. F. Song, L. Cronin, JACS, 2017, 139, 5930

(36)  “A metamorphic inorganic framework that can be switched between eight single-crystalline states”

C. Zhan, J. Cameron, D. Gabb, T. Boyd, R. Winter, L. Nadal, S. G. Mitchell, S. Glatzel, J. Breternitz, D. Gregory, D. Long, A. Macdonell and L. Cronin, Nature Communications, 2017, 8, 14185.

(35) “Removal of multiple contaminants from water by polyoxometalate – supported ionic liquid phases (POM-SILPs)”

S. Herrmann, L. De Matteis, J. M. de la Fuente, S. G. Mitchell* and Carsten Streb*, Angew. Chem. Int. Ed. 2017, 56, 1667–1670

(34)  “Instantaneous formation of polyoxometalate-based cerium vanadium oxide gels”

A. Seliverstov, M. Rangus, M. Hartmann, S. G. Mitchell, and C. Streb, Inorg. Chem. Frontiers 2017, 4, 160-164.

(33) “Gold Nanoprism-Nanorod Face Off: Comparing heating efficiency, cellular internalisation and thermoablation capacity”

G. Alfranca, A. Artiga, G. Stepien, M. Moros, S. G. Mitchell*, J. M. de la Fuente*, Nanomedicine 2016, 11, 2903-2916.

(32)  “In vitro cell cytotoxicity profile and morphological response to polyoxometalate-stabilised gold nanoparticles”

Maicas Gabas, G. Stepien, M. Moros,* S. G. Mitchell* and Jesús M. de la Fuente, New J. Chem., 201640, 1029.

(31)  “Mechanistic insights into the activation process in electrocatalytic ethanol oxidation by phosphomolybdic acid-stabilised palladium(0) nanoparticles (PdNPs@PMo12)”

Khadempir, A. Ahmadpour*, M. Taghi Hamed Mosavian, N. Ashraf, F. F. Bamoharram, R. Fernández-Pacheco, Jesús M. de la Fuente and S. G. Mitchell*, RSC Adv. 2016, 6, 5359.

(30)  “On the formation of gold nanoparticles from [AuIIICl4] and a non-classical reduced polyoxomolybdate as electron source: quantum mechanical modelling and experimental study”

Z. Lang, I. Maicas Gabas, X. Lopez, A. Clotet, J.M de la Fuente, S. G. Mitchell* and J. M Poblet*, New J. Chem., 2016, 40, 1029.

(29)  “A polyoxometalate-assisted approach for synthesis of Pd nanoparticles on graphene nanosheets: synergistic behaviour for enhanced electrocatalytic activity”

S. Khadempir, A. Ahmadpour, M. T. Hamed Mosavian, N. Ashraf, F. F. Bamoharram, S. G. Mitchell, J. M. de la Fuente, RSC Advances 2015, 5, 24319-24326.

(28) “Dissecting the molecular mechanism of apoptosis during photothermal therapy using gold nanoprisms”

M. Pérez-Hernández, P. del Pino, S. G. Mitchell, M. Moros, G. Stepien, B. Pelaz, W. Parak, E. Gálvez, J. Pardo and J. M. de la Fuente, ACS Nano, 2015, 9, 52–61.

(27)  “The importance of a correct functionalization of gold and magnetic nanoparticles for bioapplications”

R. M. Fratila, S. G. Mitchell, P. del Pino, V. Grazú, J. M. de la Fuente, Langmuir, 2014, 30 (50), 15057–15071 (HIGHLIGHTED ON THE FRONT COVER)

(26)  “Supramolecular Antimicrobial Capsules Assembled from Polyoxometalates and Chitosan”

L. De Matteis, S. G. Mitchell* and J. M. de la Fuente, J. Mater. Chem. B, 2014, 2, 7114-7117.

(25)  “Towards Polyoxometalate‐Cluster‐Based Nano‐Electronics”

L. Vilà-Nadal, S. G. Mitchell, S. Markov, C. Busche, V. Georgiev, A. Aseov, L. Cronin, Chem. A Euro J. 2013, 19, 16502-16511.

(24)  “Simultaneous syntheses of polyoxometalates and metal nanoparticles from molecular precursors: redox-active microreactors and functional nanomaterials.”

S. G. Mitchell* and J. M. de la Fuente, Eur. J. Inorg. Chem. 2013, 32, 5517-5522. (HIGHLIGHTED ON THE FRONT COVER)

(23)  “The fate of nanocarriers as nanomedicines in vivo: important considerations and biological barriers to overcome”

S. G. Mitchell, M. Moros, V. Grazú, J. M. de la Fuente, Current Medicinal Chemistry, 2013, 20, 2759-78.

(22)  “Design and Characterization of Functional Nanoparticles for Enhanced Bio-Performance”

P. del Pino, S. G. Mitchell, B. Pelaz, Immobilization of Enzymes and Cells, 2013 165-207.

(21)  “Transfer of large, highly-charged polyoxometalates into organic media via a third phase”

D. Gabb, C. P. Pradeep, S. G. Mitchell, H. N. Miras, T. Boyd, D.-L. Long, L. Cronin, Polyhedron, 2013, 52, 159-164.

(20)  “The synergistic behavior of polyoxometalates and metal nanoparticles: From synthetic approaches to functional nanohybrid materials”

S. G. Mitchell* and J. M. de la Fuente, J. Mater. Chem. 2012, 22, 18091-18100.

(19)  “Organic-soluble lacunary {M2P2W15} polyoxometalate sandwiches with previously unseen αββα isomerism”

D. Gabb, C. P. Pradeep, H. N. Miras, S. G. Mitchell, T. Boyd, D.-L. Long, L. Cronin, Dalton Trans. 2012, 41, 10000-10005.

(18)  “Exploring the Rotational Isomerism in Non–Classical Wells–Dawson Anions {W18X}: A Combined Theoretical and Mass Spectrometry Study.”

L. Vilà-Nadal, S. G. Mitchell, D. –L. Long, A. Rodríguez-Fortea, X. López, J. M. Poblet, L. Cronin, Dalton Trans., 2012, 41, 2264-2271. (HOT ARTICLE).

(17) “The Crown-Type [P8W48O184]40- Heteropolyanion and the Structure-Directing Role of the Cation Templates“

T. Boyd, S. G. Mitchell, D. Gabb, D.-L. Long, L. Cronin, Chemistry: A Euro. J., 2011,17, 12010-12014. (HIGHLIGHTED ON THE INSIDE COVER).

(16) “Nucleation Mechanisms of Heteropolyoxometalates: A Combined Theoretical and Mass Spectrometry Study.”

L. Vilà-Nadal, S. G. Mitchell, A. Rodríguez-Fortea, H. N. Miras, L. Cronin, J. M. Poblet, Phys. Chem. Chem. Phys., 2011, 13, 20136-20145. (HIGHLIGHTED ON THE FRONT COVER).

(15)  “A Mixed Valence Manganese Cubane Trapped By Inequivalent Trilacunary Polyoxometalate Ligands”

S. G. Mitchell, P. I. Molina, S. Khanra, H. N. Miras, A. Prescimone, G. J. T. Cooper, R. S. Winter, E. K. Brechin, D.-L. Long, R. J. Cogdell, L. Cronin, Angew. Chem. Int. Ed., 2011, 50, 9154-9157.

(14)  “Self-Assembly of a Family of Macrocyclic Polyoxotungstates with Emergent Material Properties”

J. Gao, J. Yan, S. G. Mitchell, H. N. Miras, A. G. Boulay, D.-L. Long, L. Cronin, Chem. Sci., 2011, 2, 1502-1508.

(13)  “Extended Polyoxometalate Framework Solids: Two Novel Mn(II)-Linked {P8W48} Network Arrays”

S. G. Mitchell, T. Boyd, H. N. Miras, D.-L. Long, L. Cronin, Inorg. Chem., 2010, 50, 136-143.

(12)  “A Novel Dimeric Polyoxometalate Sandwich Motif Containing a Truncated {Mn3O4} Cubane Core”

S. G. Mitchell, H. N. Miras, D.-L. Long, L. Cronin, Inorg. Chim. Acta., 2010, 363, 4240-4246.

(11)  “Designed Modular Inorganic Polyoxometalate Frameworks showing Emergent Properties: Redox Alloys”

J. Thiel, C. Ritchie, H. N. Miras, C. Streb, S. G. Mitchell, T. Boyd, M. N. Corella Ochoa, M. H. Rosnes, J. McIver, D.-L. Long, L. Cronin, Angew. Chem. Int. Ed., 2010, 49, 6984-6988.

(10) “The influence of carbon laydown on selectivity in the hydrogenation of pentenenitriles over supported-nickel catalysts”

J. McGregor, A. S. Canning, S. Mitchell, S. D. Jackson, L. F. Gladden, Appl. Catal. A: General, 2010, 384, 192-200.

(9)   “Understanding and Mapping the Assembly of a Family of Trimeric Polyoxometalates: Transition Metal Mediated Wells-Dawson {M18}-Trimers”

T. Boyd, S. G. Mitchell, H. N. Miras, D.-L. Long, L. Cronin, Dalton Trans., 2010, 39, 6460-6465.

(8)    “Face-Directed Self-Assembly of an Electronically Active Archimedean Polyoxometalate Architecture”

S. G. Mitchell, C. Streb, H. N. Miras, T. Boyd, D.-L. Long, L. Cronin, Nature Chemistry, 2010, 2, 308-312.

(HIGHLIGHTED IN Nature 2010, 464, 366).

(7)    “The Trinity of Polyoxometalates: Connecting {M12} Keggin and {M18} Dawson clusters to Triangles”

S. G. Mitchell, S. Khanra, H. N. Miras, T. Boyd, D.-L. Long, L. Cronin, Chem. Commun., 2009, 2712-2714.

(6)   “Controlling Nucleation of the Cyclic Heteropolyanion {P8W48}: Two Novel Cobalt-Substituted Phosphotungstate Networks”

S. G. Mitchell, D. Gabb, C. Ritchie, N. Hazel, D.-L. Long, L. Cronin, CrystEngComm., 2009, 11, 36-39.

(5)   “Isolation of Extendable Transition Metal Incorporated Polyoxometalate Intermediates with Structural Control”

S. G. Mitchell, C. Ritchie, D.-L. Long, L. Cronin, Dalton Trans., 2008, 1415-1417.

(4)   “Reversible Redox Reactions in an Extended Polyoxometalate Framework Solid”

C. Ritchie, C. Streb, J. Thiel, S. G. Mitchell, H. N. Miras, D.-L. Long, T. Boyd, R. D. Peacock, T. McGlone, L. Cronin, Angew. Chem. Int. Ed., 2008, 47, 1-5.

(3)   “Unravelling the Complexities of Polyoxometalates in Solution Using Mass Spectrometry: Protonation versus Heteroatom Inclusion”

D.-L. Long, C. Streb, Y.-F. Song, S. G. Mitchell, L. Cronin, J. Am. Chem. Soc., 2008, 130, 1830-1832.

(2)   “Identification, by Selective Poisoning, of Active Sites on Ni/Al2O3 for Hydrogenation and Isomerisation of cis-2-pentenenitrile”

A. S. Canning, S. D. Jackson, S. Mitchell, Catalysis Today, 2006, 114, 372–376.

(1)   “Synthesis of Atropoisomeric Pyridines via Cobalt-Catalyzed Cocyclotrimerization of Diynes with Benzonitrile”

R. Hrdina, I. G. Stará, L. Dufková, S. Mitchell, I. Císarŏvá, M. Kotora, Tetrahedron, 2006, 62, 968–976.

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